Thursday, 8 September 2005

This presentation is part of: Poster Session II

A charge-transfer gas ion source with isobar separation for Cl-

J. Doupé, Earth and Atmospheric Sciences, University of Alberta, 1-26 Earth Sciences Bldg., Edmonton, AB T6G 2E3, Canada and A. E. Litherland, IsoTrace Laboratory, University of Toronto, 60 Saint. George St., Toronto, ON M5S 1A7, Canada.

Sputter ion sources are generally used in Accelerator Mass Spectrometry (AMS) because they produce high currents and very little memory effect. However, gas sources are promising for AMS because of their potential for isobar attenuation. In this study a gas ion source was designed based on electron transfer from a primary negative ion beam (20 keV energy) to an iodine monochloride (ICl) gas target.  ICl is promising for 36Cl work, because its sulphur analogue, disulphur diiodide (S2I2) is thermodynamically unstable at room temperature. In a preliminary phase of this work, the total electron loss cross-sections of various ions in ICl were investigated.  These cross-sections for Cu- and Sn- on ICl at 20 keV were determined to be 8 x 10-15 cm2 and 1.2 x 10-14 cm2 respectively, consistent with values expected for resonant electron transfer, allowing for the Franck-Condon principle. Atoms with higher and lower electron affinities had lower cross section as expected. During the design phase, longitudinal ion extraction geometry was selected for the ion source. Although this simplified the design, it also led to a significant energy spread in the extracted ions.  Test runs of the ion source indicated that relatively high ion extraction efficiencies could be achieved. With a primary beam of Cu-, and a quadratic axial potential for extraction, the secondary beam of Cl- was about 20% as large as the Cu- beam.  Mass spectra showed that I-, Cl-, ICl-, and I2- were all extracted from the cell.  The Cu- beam produced the most favourable ratio (2.6) of Cl-/ICl- whereas the value for a S- beam was lowest at 0.76. Overall this study has validated the basic concept of a resonant charge transfer gas ion source.  Future studies will concentrate on improvements to the ion extraction geometry using, for example, a radio-frequency mulipole with a small longitudinal electric field gradient.

 


See more of Poster Session II
See more of The 10th International Conference on Accelerator Mass Spectrometry (September 5-10, 2005)